The 22-year-old won the penalty that Paul Pogba converted at the second attempt in the 27th minute before lashing home what proved the victor just after half-time.
77' - GOAL! Man United 2-1 Everton.
Manager Jose Mourinho, who has criticised the player in the past this season, on this occasion took to the 25-year-old's defence, arguing that he likes to see players be courageous and stating that he has no interest in "Mickey Mouse" players who shirk responsibility in such situations.
Five minutes later another United attack down the Everton right saw Rashford net after Pickford could only parry a shot from Pogba, but the flag was already up for offside.
The theme of the build-up to the match from Everton's perspective had been Marco Silva's assertion that he would take his side to Manchester looking to beat the erratic Red Devils and that showed in a decent opening during which they forced the first save the contest. In football it's hard to feed that relation with managers, because our life is not an easy one and it's not like we can have conversations or be together every day or every week, but he's a good boy.
'The thing I like is the desire to take it, ' Mourinho said.
"In the last nine matches between Lukaku and Rashford they have scored one goal if I am not wrong".
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'It is hard periods for them and for me because I want more from them but I am really happy with Anthony.
Everton can be definitely be aggrieved with the referee for having wrongly awarded United the penalty which made it 1-0. When the game is balanced in the first 20-25 minutes, the penalty starts to put them ahead in the match and more comfortable.
Romelu Lukaku's omission from the starting XI afforded Martial a prominent role and it was his quick feet that drew the penalty from Idrissa Gueye, who did get a toe to the ball before the attacker's theatrical fall.
"Sometimes we decide the best thing for the player is not to be on the pitch, but to be protected, away from the pressure".
Chelsea is unbeaten and in second place, two points behind Liverpool.
Everton were then gifted a way back into proceedings with 13 minutes remaining after Pogba gave away possession as stupidly as the sliding challenge that followed from Smalling on Richarlison inside the box.
With six extra minutes indicated, Blues fans raised their voices for a final onslaught in search of an equaliser that would have been deserved, but it was Pickford who again proved vital denying Martial as he was played into oceans of space, the England 'keeper coming out on top.
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